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• W2085367415 abstract "Abstract Irradiation of the polycrystalline n-CdSe/metal as the septum electrode of an electrochemical photovoltaic cell with visible light (λ > 390 nm) evolves hydrogen at the metal surface without an externally applied voltage. The semiconductor septum electrode, modeled after the photosynthetic thylakoid membrane, separates two aqueous solutions; the one exposed to light and in contact with the n-CdSe side consists of NaOH, Na2S and S (all at 1 M). The other electrolyte, not illuminated but in contact with the metal surface, is either H2SO4 (5 M), Na2SO4 (0.5 M) + H2SO4 (2 M), or artificial sea water. The rate of hydrogen evolution of the cell increases with decreasing load resistance, being maximal under short-circuit conditions. Thus, the cell is capable of converting visible light of the solar spectrum to stored chemical fuel and into electricity concurrently. These findings may open the way for process-scale photoelectrolysis of sea water and/or for generating electricity using sunlight." @default.
• W2085367415 created "2016-06-24" @default.
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• W2085367415 date "1990-01-01" @default.
• W2085367415 modified "2023-09-24" @default.
• W2085367415 title "Hydrogen production from water by semiconductor septum electrochemical photovoltaic cell using visible light" @default.
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• W2085367415 doi "https://doi.org/10.1016/0360-3199(80)90004-x" @default.
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