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- W2085369841 abstract "l-Glutamic acid diketopiperazine ω-alkenyl esters were synthesized and polymerized via acyclic diene metathesis polycondensation chemistry using ruthenium catalysts. The polycondensation of l-glutamic acid diketopiperazine ω-allyl ester (1) was unsuccessful, while the polycondensation of l-glutamic acid diketopiperazine ω-homoallyl ester (2), -pentenyl ester (3), and -hexenyl ester (4) with Grubbs second-generation catalyst and Grubbs−Hoveyda catalyst satisfactorily proceeded to give the corresponding polymers. They exhibited melting temperatures around 150 °C, and possessed crystalline structures similar to that of polyethylene. Dynamic light scattering and differential scanning calorimetric measurements suggested that the polymers formed aggregates in N,N-dimethylformamide, presumably based on hydrogen bonding between diketopiperazine moieties." @default.
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- W2085369841 date "2008-07-23" @default.
- W2085369841 modified "2023-10-09" @default.
- W2085369841 title "ADMET Polycondensation of Diketopiperazine-Based Dienes. Polymerization Behavior and Effect of Diketopiperazine on the Properties of the Formed Polymers" @default.
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- W2085369841 doi "https://doi.org/10.1021/ma800367z" @default.
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