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- W2085380063 abstract "Abstract A method has been developed for extrapolating vapour pressures of pure substances below 1,300 Pa. It is based on the integration of the Clausius Clapeyron equation, with a suitable expression of the integrating function. The vaporization enthalpy is extrapolated according to the Majer-Svoboda equation with parameters fitted on enthalpy values calculated from available data on vapour pressure above 1,300 Pa. The modified two-parameter Miller equation is used in vapour pressure data reduction. The change of molar volume is expressed by means of a modified Redlich-Kwong equation of state. The procedure is devised so that only vapour pressure data in the range 1,300–100,000 Pa and critical temperature are needed for calculation. Results obtained with this method are compared for many compounds with available and selected vapour pressure data in the range 0.3–100 Pa. In conclusion, the proposed procedure ensures a good prediction of very low vapour pressures. When reliable and smooth pressure data are available at normal pressure, direct extrapolation of the Miller equation also gives good results, due to its small number of parameters." @default.
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- W2085380063 date "1991-08-01" @default.
- W2085380063 modified "2023-09-23" @default.
- W2085380063 title "A METHOD FOR ESTIMATING VAPOUR PRESSURES OF PURE HIGH BOILING SUBSTANCES" @default.
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- W2085380063 doi "https://doi.org/10.1080/00986449108911542" @default.
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