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- W208538331 abstract "The combination of cocatalysts for simultaneously promoting rapid transfer of photogenerated electrons and holes is one of the effective strategies to improve photocatalytic activity of semiconductor photocatalysts. In this study, highly efficient TiO2 photocatalyst with co-modification of F and Fe(III) ions was prepared by a facile two wet-chemical method including Fe(III) ions impregnation and then F-ion adsorption on the TiO2 surface. The photocatalytic results demonstrated that the simultaneously modified Fe(III)/F-TiO2 photocatalyst exhibited obvious enhancement of photocatalytic performance compared with the pure TiO2 and single-component modified Fe(III)/TiO2 and F-TiO2. Based on the present experimental results, we propose a possible synergistic effect of Fe(III) and F ions to illustrate the enhanced photocatalytic activity of Fe(III)/F-TiO2 photocatalyst, namely the Fe(III) ions act as effective active sites to rapidly transfer the photogenerated electrons in the CB of TiO2 and then reduce oxygen, while F ions work as other effective active sites to rapidly transfer the photogenerated holes in the VB of TiO2 and then form free hydroxide radical to oxidize the organic substances. As a result, the transfer rate and the interfacial catalytic reaction of photogenerated electrons and holes were simultaneously accelerated, which resulted in the enhanced photocatalytic performance of Fe(III)/F-TiO2 photocatalyst. Due to the low cost and abundant resource of Fe and F, the obtained photocatalyst is promising for practical application. Furthermore, the present work can provide some good ideas for the rational preparation of new and high-efficiency photocatalysts." @default.
- W208538331 created "2016-06-24" @default.
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- W208538331 date "2015-10-01" @default.
- W208538331 modified "2023-10-14" @default.
- W208538331 title "Co-modification of F− and Fe(III) ions as a facile strategy towards effective separation of photogenerated electrons and holes" @default.
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- W208538331 doi "https://doi.org/10.1016/j.apsusc.2015.05.056" @default.
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