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- W2085384894 abstract "The precipitation of soduim urate from solutions containing uric acid, soduim hydroxide, hydrochloric acid, sodium chloride and water was investigated at constant pH (7.5±0.1) and temperature (308 K). Precipitates were observed by lights and electron microscopy and characterized by electron and X-ray diffraction. The results are presented in the form of “precipitation” and “chemical potential” diagrams, the latter giving the soduim-to-urate molar ratios of the precipitates. Two types of precipitation boundaries were observed, both of which had indicated soduim-to-urate moral ratios of 1:1. The ion activity product, (Na+)(HU-), associated with boundary I was API=(4.8±1.1)×10-5 and with boundary II was with boundary II was APII=(6.5±0.4)×10-4. The supersaturation, S, at boundary II was S=APII/Ksp=12.3, in which Ksp is the solubility product of soduim acid urate monohydrate. The latter precipitated as well-formed crystals at supersaturations of 12.3 and above. The ion activity product associated with boundary I is approximately equal to the solubility product of soduim acid urate monohydrate. Small amounts of several morphologically different sodium urate crystals formed in the range of supersaturations (1≤S≤12.3). Crystals formed in this range may include the monohydrate of sodium acid urate and possibly a higher hydrate. The findings have relevance to pathological renal stone formation and gouty arthritis." @default.
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- W2085384894 date "1987-07-01" @default.
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- W2085384894 title "Precipitation of sodium acid urate from electrolyte solutions" @default.
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- W2085384894 doi "https://doi.org/10.1016/0022-0248(87)90252-1" @default.
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