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- W2085385598 abstract "Evidence is reported that thiirenium ions are involved as intermediates in both the addition of benzenesulphenyl chloride to diarylacetylenes and in unimocular substitution reactions of β-phenylthiovinyl sulphonates. The thiirenium ion generated from 1,2-diphenyl-2-phenylthiovinyl 2,4,6-trinitrobenzenesulphonate undergoes nucleophilic attack by chloride ion both at the carbon atoms to give 1,2-diphenyl-2-phenylthiovinyl chloride and at the sulphur atom to give diphenylacetylene and benzenesulphonyl chloride which can be trapped by added scavengers." @default.
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- W2085385598 date "1973-01-01" @default.
- W2085385598 modified "2023-10-16" @default.
- W2085385598 title "Formation and reactivity of thiirenium ions" @default.
- W2085385598 doi "https://doi.org/10.1039/p29730000493" @default.
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