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- W2085388538 startingPage "8018" @default.
- W2085388538 abstract "Cu2ZnSnS4 (CZTS) is a promising p-type semiconductor that has not yet been extensively investigated for solar fuel production via water splitting. Here, we optimize and compare two different electrodeposition routes (simultaneous and sequential) for preparing CZTS electrodes. More consistent results are observed with the simultaneous route. In addition, the effect of etching and the presence of a CdS buffer layer on the photocurrent are investigated. Finally, we demonstrate for the first time the stabilization of these electrodes using protecting overlayers deposited by atomic layer deposition (ALD). Our best performing protected electrodes (Mo/CZTS/CdS/AZO/TiO2/Pt) exhibited a photocurrent of over 1 mA cm–2 under standard one sun illumination conditions and a significant improvement in stability over unprotected electrodes." @default.
- W2085388538 created "2016-06-24" @default.
- W2085388538 creator A5024625560 @default.
- W2085388538 creator A5044915266 @default.
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- W2085388538 date "2013-08-14" @default.
- W2085388538 modified "2023-10-14" @default.
- W2085388538 title "Optimization and Stabilization of Electrodeposited Cu<sub>2</sub>ZnSnS<sub>4</sub> Photocathodes for Solar Water Reduction" @default.
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- W2085388538 doi "https://doi.org/10.1021/am402096r" @default.
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