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- W2085392788 abstract "Some chiral methyl branched alkanoic and alkenoic acids were used as substrates in esterifications with 1-hexadecanol in cyclohexane at water activity aw=0.8 catalysed by immobilised Candida rugosa lipase (CRL). Citronellic acid was one of several chiral 2- and 3-methyl branched acids that were successfully resolved by the catalyst. With 3-methyl-branched substrates the R-enantiomers reacted fastest, whereas with 2-methyl acids the lipase generally displayed S-preference except in one case where it displayed R-preference. When a double bond was present in the chain, the selectivity of CRL (E=24–51) was greater compared with the corresponding saturated acid (E=17–23). Attempted transesterifications of vinyl acetate with some chiral 2- or 3-methyl branched primary alcohols using crude CRL gave very low E-values (E=1–2)." @default.
- W2085392788 created "2016-06-24" @default.
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- W2085392788 date "1999-05-01" @default.
- W2085392788 modified "2023-10-16" @default.
- W2085392788 title "Candida rugosa lipase as an enantioselective catalyst in the esterification of methyl branched carboxylic acids: resolution of rac-3,7-dimethyl-6-octenoic acid (citronellic acid)" @default.
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- W2085392788 doi "https://doi.org/10.1016/s0957-4166(99)00178-0" @default.
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