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- W2085395206 abstract "Radiation-induced solid-state polymerization in binary systems containing long-chain compounds has been investigated. Butyl stearate–methyl methacrylate and stearyl alcohol–methyl methacrylate systems have been studied in detail. In these systems insource polymerization does not occur but a remarkable post-polymerization takes place on warming after irradiation at low temperature. The limiting conversion characteristics of this post-polymerization depend greatly on the nature and the concentration of the long-chain compounds. The post-polymerization is observed to be more marked in the butyl stearate–methyl methacrylate system than in the stearyl alcohol–methyl methacrylate system, and it increases with increasing concentration of the long-chain component. An optimum warming rate and warming temperature exists for the maximum saturated conversion. Irradiation in air causes some decrease of conversion compared to irradiation in vacuo. The possible mechanism is that monomer diffuses into the crystals of the long-chain compound after melting at the eutectic temperature. The polymerization may be initiated by trapped radicals of the long-chain compound and carried out in the crystal of the long-chain compound with a smaller possibility of termination. In binary systems containing long-chain compounds, lowering of the melting point is slight, and the eutectic composition exists at the richer composition of monomer, so almost all the long-chain substance remains as excess crystals, which are suitable for holding trapped radicals. The crystal lattices of long-chain compounds may be softer than those of compounds of small molecular size. This fact is favorable for monomer diffusion. This explains why such a post-polymerization takes place only in systems containing long-chain molecules." @default.
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- W2085395206 date "1967-07-01" @default.
- W2085395206 modified "2023-09-27" @default.
- W2085395206 title "Radiation-induced solid-state polymerization in binary systems. V. Polymerization in binary systems containing long chain compounds" @default.
- W2085395206 doi "https://doi.org/10.1002/app.1967.070110709" @default.
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