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• W2085405219 endingPage "844" @default.
• W2085405219 startingPage "835" @default.
• W2085405219 abstract "A thermodynamic analysis of the Fe–Nb–B ternary system has been carried out by estimating the unknown thermodynamic properties of various borides and solid solutions with using a first-principles method. The calculations showed that, at least in the ground state, the solid solution, in which the B atoms substitute for the Fe atoms, was more probable than that where the B atoms dissolved in the octahedral interstitial sites. Furthermore, the calculated values for the binary borides in the Fe–B and Nb–B systems were in reasonable agreement with those found by experiment. The thermodynamic properties such as formation enthalpies for the FeNbB and Nb3B2 phases were also determined for ternary borides. The thermodynamic functions determined using these theoretical values, as well as the available experimental information on the phase boundaries, successfully revealed the phase equilibria in the Fe–Nb–B ternary system over the entire composition and temperature ranges." @default.
• W2085405219 created "2016-06-24" @default.
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• W2085405219 date "2008-01-01" @default.
• W2085405219 modified "2023-10-01" @default.
• W2085405219 title "Thermodynamic Analysis of the Fe–Nb–B Ternary System" @default.
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• W2085405219 doi "https://doi.org/10.2355/isijinternational.48.835" @default.
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