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• W2085405896 endingPage "956" @default.
• W2085405896 startingPage "941" @default.
• W2085405896 abstract "A family of mixed (iminophosphoranyl)(selenophosphoranyl)methane ligands of general composition Ph2P(Se)CH2P(NR)Ph2 have been synthesized by oxidation of Ph2PCH2P(NR)Ph2 with elemental selenium. In the presence of Et3N, these ligands react with [{RuCl(μ-Cl)(η6-p-cymene)}2] to afford mononuclear Ru(II) species in which the resulting methanide anions adopt a tridentate coordination. Further deprotonation with KH generates carbenic ruthenium derivatives which participate, under remarkably mild conditions, in C–C coupling processes with isocyanides." @default.
• W2085405896 created "2016-06-24" @default.
• W2085405896 creator A5013565916 @default.
• W2085405896 creator A5023621482 @default.
• W2085405896 creator A5026483743 @default.
• W2085405896 creator A5089737177 @default.
• W2085405896 date "2010-01-01" @default.
• W2085405896 modified "2023-10-14" @default.
• W2085405896 title "Access to the first (iminophosphoranyl)(selenophosphoranyl)methane ligands Ph₂P(Se)CH₂P(NR)Ph₂: coordination of their methanide and methandiide anions to ruthenium" @default.
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