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- W2085408317 abstract "Temperature-dependent specific heat, magnetic susceptibility, and resistance measurements have been carried out to study the electronic state of Yb ion in Yb 2 Ni 12 (P,As) 7 . All the measurements identify a valence fluctuating state for the Yb in both compounds. The electronic contributions to the specific heat, γ , are enhanced compared to those of the corresponding Yttrium compounds. The γ is temperature dependent (increasing with lowering temperature) for Yb 2 Ni 12 P 7 and temperature independent for Yb 2 Ni 12 As 7 . The parameters of valence fluctuation for the Yb ion are calculated from magnetic susceptibility using the ICF model and were found to be T sf ≈68 K, E ex ≈278 K and T sf ≈204 K, E ex ≈1709 K, resulting in the Yb valence of 2.21 and 2.79, for Yb 2 Ni 12 (P,As) 7 , respectively." @default.
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- W2085408317 date "1998-10-01" @default.
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- W2085408317 title "Intermediate valence behavior of Yb in Yb2Ni12(P,As)7" @default.
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- W2085408317 doi "https://doi.org/10.1016/s0921-4526(98)00383-4" @default.
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