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• W2085408879 abstract "[reaction: see text]. Two novel chiral hydrazine resins for asymmetric solid-phase synthesis have been developed. The enantiopure beta-methoxyamino auxiliaries, derived from trans-4-hydroxy-(S)-proline and (R)-leucine, were attached to Merrifield resin and transformed into their corresponding hydrazines. Immobilization of various aldehydes, followed by 1,2-addition of organolithium reagents to the resulting enantiopure hydrazones and reductive cleavage from the solid support, furnished alpha-branched amines, which were isolated as their corresponding amides in good overall yields and enantiomeric excesses of up to 86%." @default.
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• W2085408879 date "2001-03-22" @default.
• W2085408879 modified "2023-10-16" @default.
• W2085408879 title "Asymmetric Synthesis of α-Branched Primary Amines on Solid Support via Novel Hydrazine Resins" @default.
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• W2085408879 doi "https://doi.org/10.1021/ol015721x" @default.
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