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- W2085427789 abstract "Abstract The enthalpies of solution of 90K superconducting YBa 2 Cu 3 O 6.91 in 1N HCl aqueous solution has been measured calorimetrically at 298K. In combination with auxilliary values from literatures, the standard enthalpies of formation of YBa 2 Cu 3 O 6.91 has been derived. The value of Δ f H m °(YBa 2 Cu 3 O 6.91 ) is estimated 3027 ± α kJ / mol (α is from the auxilliary values and experimental error and is less than 5). By use of entropy value of YBa 2 Cu 3 O 6.91 . we found an increase in the stability of the compound relative to the parent oxides (Y 2 O 3 , BaO and CuO) from 300K up to 1156K. These results explain why the superconducting YBC oxide has a tendency to decompose above 1200K in the thermodynamic view point." @default.
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- W2085427789 date "1991-12-01" @default.
- W2085427789 modified "2023-10-11" @default.
- W2085427789 title "A solution calorimetric study on stability of superconducting YBa2Cu3O6.91" @default.
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- W2085427789 doi "https://doi.org/10.1016/0921-4534(91)91610-g" @default.
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