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• W2085428221 abstract "Abstract In this work polarization characteristics and “service life” test of the non-noble metal composite coatings Ni–MoO x and Ni–MoO 2 for hydrogen evolution reaction (HER) in 32 wt.% NaOH at 90 °C were investigated and compared with that recorded for De Nora's commercial Ni + RuO 2 cathode coating (DN). It was shown that under conditions of industrial application in the “zero-gap” membrane cells the lowest over-voltage for HER has been recorded for the Ni–MoO 2 coating. At the same time the “service life” test was performed on all three electrodes in the same solution. This test was based on monitoring the current density response before and after repetitive cycling of these electrodes with 50 mV s −1 in the potential range from hydrogen (−1.25 V vs. SCE) to oxygen (0.50 V vs. SCE) evolution. It was shown that the activity for all electrodes at the end of a “service life” test dropped to approximately 54% of the initial value, being comparable with the results obtained for Pt-based cathodes. The SEM–EDS analysis of the electrodes after the “service life” test showed that the Ni–MoO 2 is much more stable than the Ni–MoO x composite coating and could be promising replacement for the commercial cathode." @default.
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• W2085428221 date "2012-02-01" @default.
• W2085428221 modified "2023-09-25" @default.
• W2085428221 title "Service life test of non-noble metal composite cathodes for hydrogen evolution in sodium hydroxide solution" @default.
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• W2085428221 doi "https://doi.org/10.1016/j.electacta.2011.12.078" @default.
• W2085428221 hasPublicationYear "2012" @default.
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