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- W2085452878 abstract "Solid state reaction diffusion between pure Cu and Zr in the temperature range from 973 to 1153 K has been studied. All six intermetallic compounds Cu9Zr2, Cu51Zr14, Cu8Zr3, Cu10Zr7, CuZr and CuZr2 shown in the equilibrium phase diagram of the CuZr system have been observed in the diffusion zone above 1128 K, although the Cu10Zr2 phase appears after an incubation time at 1128 K and cannot be observed below 1098 K. About 93% of the total thickness of the six intermetallic compound layers is occupied by the first and second phases on the Cu side, Cu9Zr2 and Cu51Zr14. The layer growth of the five phases except the Cu10Zr7 phase and of the β-Zr phase (Zr-rich solid solution) has been found to obey a parabolic law in the whole temperature range. The temperature dependence of the square of the growth rate constants of these compound layers shows linear Arrhenius relationships, while that of the β-Zr layer shows a bending near the α—β transition temperature of Zr. The interdiffusion coefficients of the major phases Cu9Zr2 and Cu51Zr14 and of the β-Zr phase show linear Arrhenius relationships." @default.
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- W2085452878 date "1994-11-01" @default.
- W2085452878 modified "2023-09-23" @default.
- W2085452878 title "Reaction diffusion in the CuZr system" @default.
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- W2085452878 doi "https://doi.org/10.1016/0925-8388(94)90862-1" @default.
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