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- W2085455516 abstract "The doubly bridged dinuclear (μ-oxo)titanium complex (Me2C)(Me2Si)(C5H3)2(μ-O)(CpTiCl)2 (1) was synthesized by the reaction of the lithium compound of the doubly bridged bis(cyclopentadienyl) ligand with (CpTiCl2)2O. Treatment of 1 with concentrated HCl or HBr gave the corresponding Cp-decoordinated products (Me2C)(Me2Si)(C5H3)2[CpTiX(μ-O)TiX2] (X = Cl (2), Br (3)). All these titanium complexes were characterized by 1H NMR, 13C NMR, MS spectra, and elemental analysis. The crystal structures of (CpTiCl2)2O, 1, and 3 were determined by X-ray diffraction. Their catalytic properties for ethylene polymerization were also studied in the presence of MAO." @default.
- W2085455516 created "2016-06-24" @default.
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- W2085455516 date "2009-04-23" @default.
- W2085455516 modified "2023-10-16" @default.
- W2085455516 title "Synthesis, Structures, and Polymerization Catalytic Properties of Doubly Bridged Bis(cyclopentadienyl) Dinuclear (μ-Oxo)titanium Complexes" @default.
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- W2085455516 doi "https://doi.org/10.1021/om900089w" @default.
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