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- W2085459815 abstract "Fragmentation of lead cluster ions (Pb N + : N = 2–20) in low-energy collisions with a highly oriented pyrolytic graphite surface has been investigated by means of a tandem time-of-flight mass spectrometer. At low incident energies, all clusters fragment dominantly by an atom loss process. This behavior is characteristic for clusters of metallic elements, but in contrast to Si N + , Ge N + and Sn N + clusters. The results therefore demonstrate differences in the electronic and geometric structure between lead clusters and the lighter group-14 element clusters. The low energy dissociation patterns were compared successfully with a recent theoretical study on lead cluster fragmentation, supporting the idea, that lead clusters cations already show signatures of metallic behavior unlike Si N + , Ge N + and Sn N + clusters of the same size." @default.
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- W2085459815 date "2007-12-01" @default.
- W2085459815 modified "2023-10-09" @default.
- W2085459815 title "Surface-Induced Dissociation as a Probe for the Energetics and Structure of Lead Clusters" @default.
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- W2085459815 doi "https://doi.org/10.1524/zpch.2007.221.11-12.1569" @default.
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