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• W2085462289 abstract "V/Ti/O catalysts, active for the mild oxidation of o-xylene, were tested in the ammoxidation of different alkylaromatics. The presence of substituents on the aromatic ring was found to slightly influence the reactivity of the hydrocarbon; both electron donor and acceptor groups showed an activating effect with respect to toluene. This was taken as an indication that the slow step of the reaction consists in a homolytic scission of the C-H bond, thus involving a radical intermediate species. An influence on the selectivity to nitrile was also observed; in particular, the presence of donor groups causes a decrease in the selectivity. The presence of substituents in the 1, 2 position leads instead to an inhibition of the overall reaction rate." @default.
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• W2085462289 date "1987-11-01" @default.
• W2085462289 modified "2023-10-16" @default.
• W2085462289 title "Synthesis of aromatic nitriles by vapour phase catalytic ammoxidation" @default.
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• W2085462289 doi "https://doi.org/10.1016/0304-5102(87)87025-6" @default.
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