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• W2085467544 startingPage "6474" @default.
• W2085467544 abstract "Femtosecond time resolved photoinduced transmission studies are carried out in nanocrystalline dihexylsexithiophene films with long range structural order. The results are compared with those obtained for sexithiophene in several states of aggregation. We explain the lack of radiative recombination in the solid phase with the formation of two nonradiative excitations, dark excitons and charge transfer states. The dark exciton dynamics is studied in detail in dihexylsexithiophene films; thermalization occurs within 200 fs, then decay takes place by mutual annihilation in the first ps, and by monomolecular recombination at longer times. Optical dynamics indicates that within the pump pulse a second excitation is formed, and we assign it to charge transfer states. The latter decay monomolecularly in the hundred ps time scale." @default.
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• W2085467544 date "1999-10-08" @default.
• W2085467544 modified "2023-09-27" @default.
• W2085467544 title "Ultrafast spectroscopy of dark states in solid state sexithiophene" @default.
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• W2085467544 doi "https://doi.org/10.1063/1.479944" @default.
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