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- W2085484062 abstract "Mixed ligand complexes of ruthenium(III)edta with cytosine, uracil, 2-thiocytosine, 2-aminopyrimidine and 5-aminouracil were synthesised and characterised by elemental analysis, conductivity, infrared spectra, electronic spectra, 1H NMR, ESR and polarography. Uracil acts as a monodentate ligand coordinating to the metal ion through C2O. The ligands cytosine, 2-thiocytosine, 2-aminopyrimidine, 5- aminouracil act as bidentate ligands coordinating to the metal ion through N3 and C2O; N3 and C2SH; N3 and C2NH2; C6 and 5NH2, respectively. 5-Aminouracil forms an interesting organometallic complex. In this complex the C6 carbon of 5-aminouracil forms a covalent bond with ruthenium(III), with simultaneous coordination of the nitrogen of the exocyclic amino group to a second ruthenium atom forming a 2:2 diligand bridged bimetallic complex." @default.
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- W2085484062 date "1990-05-01" @default.
- W2085484062 modified "2023-10-17" @default.
- W2085484062 title "Mixed ligand complexes of ruthenium(III)edta with pyrimidines" @default.
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- W2085484062 doi "https://doi.org/10.1016/s0020-1693(00)80426-0" @default.
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