FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2085491431> ?p ?o ?g. }

• W2085491431 endingPage "66" @default.
• W2085491431 startingPage "59" @default.
• W2085491431 abstract "In this paper, we describe a method for the preparation of easy-to-use reversed-phase monolithic microbore columns. Polyetheretherketone (PEEK) tubing with an outer diameter of 1/16″ and an inner diameter of 1.0 mm was used as a column housing (empty column), and in it lauryl methacrylate (LMA) was copolymerized with ethylene dimethacrylate (EDMA). In order to chemically anchor the polymer monolith to the tube wall, the inner wall surface was pretreated by the following two-step procedure. (1) 50% sulfuric acid was filled into the PEEK tubing and left to stand for 6 h to generate sulfonate groups on the surface. (2) After washing with Milli-Q water, the sulfonated PEEK surface was brought into contact with 1 M glycidyl methacrylate in dichloromethane (or acetone) at 40°C for 4 h to introduce methacryloyl groups via the reaction of sulfonate groups and epoxy groups. Mechanical strength and column efficiency of the resulting monoliths were evaluated through the separation of a series of alkylbenzenes in acetonitrile-water (50:50, v/v) eluent over the flow rate range of 50-750 μL/min (corresponding to 1.7-25.5 mm/s). The poly(LMA-co-EDMA) monolith provided acceptable column efficiency of 2000 theoretical plates/10 cm (HETP value of 50 μm) for amylbenzene (separation factor k=40) and low flow resistance of 0.5 MPa/10 cm at a normal flow rate of 50 μL/min. The methacryloylated PEEK tubing tightly held the monolith, and the monolithic column exhibited good pressure resistance up to 15 MPa, allowing rapid separation at a 15-20 fold higher flow rate than normal." @default.
• W2085491431 created "2016-06-24" @default.
• W2085491431 creator A5000228820 @default.
• W2085491431 creator A5013126818 @default.
• W2085491431 creator A5055733563 @default.
• W2085491431 creator A5060717175 @default.
• W2085491431 creator A5084137822 @default.
• W2085491431 creator A5084299663 @default.
• W2085491431 date "2012-06-01" @default.
• W2085491431 modified "2023-10-18" @default.
• W2085491431 title "Chemical anchoring of lauryl methacrylate-based reversed phase monolith to 1/16″ o.d. polyetheretherketone tubing" @default.
• W2085491431 cites W179803531 @default.
• W2085491431 cites W1967883304 @default.
• W2085491431 cites W1972030711 @default.
• W2085491431 cites W1978473752 @default.
• W2085491431 cites W1979261834 @default.
• W2085491431 cites W1985423957 @default.
• W2085491431 cites W1986858064 @default.
• W2085491431 cites W1987439662 @default.
• W2085491431 cites W1992962827 @default.
• W2085491431 cites W1994201463 @default.
• W2085491431 cites W1998422178 @default.
• W2085491431 cites W2010273557 @default.
• W2085491431 cites W2012064155 @default.
• W2085491431 cites W2019774539 @default.
• W2085491431 cites W2021021809 @default.
• W2085491431 cites W2028027226 @default.
• W2085491431 cites W2029078471 @default.
• W2085491431 cites W2031820094 @default.
• W2085491431 cites W2039142979 @default.
• W2085491431 cites W2042714411 @default.
• W2085491431 cites W2043407648 @default.
• W2085491431 cites W2049622738 @default.
• W2085491431 cites W2050353916 @default.
• W2085491431 cites W2050547504 @default.
• W2085491431 cites W2062291757 @default.
• W2085491431 cites W2063353895 @default.
• W2085491431 cites W2070457128 @default.
• W2085491431 cites W2076974224 @default.
• W2085491431 cites W2079428293 @default.
• W2085491431 cites W2089297046 @default.
• W2085491431 cites W2093032316 @default.
• W2085491431 cites W2095984983 @default.
• W2085491431 cites W2096859507 @default.
• W2085491431 cites W2107346320 @default.
• W2085491431 cites W2114836303 @default.
• W2085491431 cites W2117879132 @default.
• W2085491431 cites W2118747976 @default.
• W2085491431 cites W2127194832 @default.
• W2085491431 cites W2156038096 @default.
• W2085491431 cites W2160569921 @default.
• W2085491431 cites W2188294725 @default.
• W2085491431 cites W2254056496 @default.
• W2085491431 cites W88808904 @default.
• W2085491431 doi "https://doi.org/10.1016/j.chroma.2012.04.030" @default.
• W2085491431 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/22560348" @default.
• W2085491431 hasPublicationYear "2012" @default.
• W2085491431 type Work @default.
• W2085491431 sameAs 2085491431 @default.
• W2085491431 citedByCount "31" @default.
• W2085491431 countsByYear W20854914312012 @default.
• W2085491431 countsByYear W20854914312013 @default.
• W2085491431 countsByYear W20854914312014 @default.
• W2085491431 countsByYear W20854914312015 @default.
• W2085491431 countsByYear W20854914312016 @default.
• W2085491431 countsByYear W20854914312017 @default.
• W2085491431 countsByYear W20854914312018 @default.
• W2085491431 countsByYear W20854914312019 @default.
• W2085491431 countsByYear W20854914312020 @default.
• W2085491431 countsByYear W20854914312021 @default.
• W2085491431 countsByYear W20854914312022 @default.
• W2085491431 crossrefType "journal-article" @default.
• W2085491431 hasAuthorship W2085491431A5000228820 @default.
• W2085491431 hasAuthorship W2085491431A5013126818 @default.
• W2085491431 hasAuthorship W2085491431A5055733563 @default.
• W2085491431 hasAuthorship W2085491431A5060717175 @default.
• W2085491431 hasAuthorship W2085491431A5084137822 @default.
• W2085491431 hasAuthorship W2085491431A5084299663 @default.
• W2085491431 hasConcept C132050475 @default.
• W2085491431 hasConcept C134871310 @default.
• W2085491431 hasConcept C152815550 @default.
• W2085491431 hasConcept C161790260 @default.
• W2085491431 hasConcept C178790620 @default.
• W2085491431 hasConcept C179998833 @default.
• W2085491431 hasConcept C185592680 @default.
• W2085491431 hasConcept C2779348937 @default.
• W2085491431 hasConcept C2780801859 @default.
• W2085491431 hasConcept C43617362 @default.
• W2085491431 hasConcept C44228677 @default.
• W2085491431 hasConcept C521977710 @default.
• W2085491431 hasConcept C7660682 @default.
• W2085491431 hasConceptScore W2085491431C132050475 @default.
• W2085491431 hasConceptScore W2085491431C134871310 @default.
• W2085491431 hasConceptScore W2085491431C152815550 @default.
• W2085491431 hasConceptScore W2085491431C161790260 @default.
• W2085491431 hasConceptScore W2085491431C178790620 @default.
• W2085491431 hasConceptScore W2085491431C179998833 @default.
• W2085491431 hasConceptScore W2085491431C185592680 @default.

• next