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- W2085492811 abstract "Novel supramolecular polymer networks were prepared by the reaction of poly(4-vinylpyridine) (P4VP) with 1,5-naphthalenedisulfonic acid (NDS), 1,3-propanedisulfonic acid (PDS), or adipic acid (AA). The IR and XPS analyses of the polymer networks revealed that the P4VP/NDS complex has a higher ionic interaction between pyridinium cation and sulfonate anion than the P4VP/PDS complex, and that hydrogen bonding interaction between pyridine and carboxylic acid predominantly contributes for the P4VP/AA complex. When the glass transition temperatures of P4VP and P4VP/proton donor (1/1) complexes are compared, the higher order was P4VP/NDS>P4VP/PDS>P4VP>P4VP/AA, in agreement with a higher degree of ionic interaction. The P4VP/PDS complex had a melting endothermic peak in the DSC thermograms, which was not observed for the P4VP/NDS complex. The thermal decomposition temperature of the P4VP complexes is also investigated in relation to the intermolecular interaction." @default.
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- W2085492811 date "2004-10-01" @default.
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- W2085492811 title "Thermal properties of novel supramolecular polymer networks based on poly(4-vinylpyridine) and disulfonic acids" @default.
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- W2085492811 doi "https://doi.org/10.1016/j.polymer.2004.09.012" @default.
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