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- W2085494443 abstract "The mechanistic aspects of the ORR catalyzed by a non-pyrolyzed Cu-based catalyst were studied using a previously reported in situ electrochemical-EPR cell. Measurements made at a series of different O 2 concentrations include calculation of Tafel slope and reaction order of O 2 and Cu species in the kinetic region. The Cu-species reaction orders reveal that Cu(I) is involved in the RDS in a 1:1 complex with O 2 and that Cu(II) reduced to Cu(I) is a fast step before the RDS." @default.
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- W2085494443 date "2014-09-25" @default.
- W2085494443 modified "2023-10-16" @default.
- W2085494443 title "Mechanistic Study of ORR by Cu(II) Based Electrocatalyst Using Simultaneous Electrochemical EPR Spectroscopy" @default.
- W2085494443 doi "https://doi.org/10.1149/06132.0001ecst" @default.
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