FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2085497894> ?p ?o ?g. }

• W2085497894 endingPage "3540" @default.
• W2085497894 startingPage "3530" @default.
• W2085497894 abstract "A total of 12 enantiopure 1,2-disubstituted and 1,2,3-trisubstituted ferrocenyl diphosphines [1-Ph2P-2-R2PCH2-3-R‘-Fc, R = Cy, t-Bu, 3,5-(CH3)2C6H3), R‘ = H, CH3, Ph, 3,5-(CH3)2C6H3)] have been synthesized, characterized, and tested in asymmetric rhodium- and ruthenium-catalyzed hydrogenations of four alkenes and two ketones. The performance of these ferrocene derivatives in catalytic hydrogenations was compared to those of catalysts based on Josiphos, PPF-t-Bu2, and Xyliphos [1-Ph2P-2-R2P(CH3)CH-Fc, R = Cy, t-Bu, 3,5-(CH3)2C6H3)]. Dichloro palladium(II) complexes of Xyliphos and its analogues lacking the stereogenic center were synthesized as model compounds, and their molecular structures were studied in solution and, for four complexes, in the solid state. In hydrogenation reactions the replacement of Xyliphos as the catalyst ligand with its analogues lacking the stereogenic center leads to changes in product configurations or significant increases or decreases in ee values." @default.
• W2085497894 created "2016-06-24" @default.
• W2085497894 creator A5006005996 @default.
• W2085497894 creator A5055756981 @default.
• W2085497894 creator A5068087465 @default.
• W2085497894 creator A5070276095 @default.
• W2085497894 creator A5077575893 @default.
• W2085497894 date "2007-06-12" @default.
• W2085497894 modified "2023-09-24" @default.
• W2085497894 title "Synthesis and Use in Asymmetric Hydrogenations of Solely Planar Chiral 1,2-Disubstituted and 1,2,3-Trisubstituted Ferrocenyl Diphosphines: A Comparative Study" @default.
• W2085497894 cites W1972772775 @default.
• W2085497894 cites W1974292676 @default.
• W2085497894 cites W1978974009 @default.
• W2085497894 cites W1992084144 @default.
• W2085497894 cites W1999651796 @default.
• W2085497894 cites W2043121450 @default.
• W2085497894 cites W2047755968 @default.
• W2085497894 cites W2064041339 @default.
• W2085497894 cites W2081472044 @default.
• W2085497894 cites W2083545872 @default.
• W2085497894 cites W2091739808 @default.
• W2085497894 cites W2331215636 @default.
• W2085497894 cites W2500210460 @default.
• W2085497894 cites W2950078230 @default.
• W2085497894 cites W2950971696 @default.
• W2085497894 cites W2951735771 @default.
• W2085497894 cites W2952258738 @default.
• W2085497894 cites W4255001492 @default.
• W2085497894 doi "https://doi.org/10.1021/om700405a" @default.
• W2085497894 hasPublicationYear "2007" @default.
• W2085497894 type Work @default.
• W2085497894 sameAs 2085497894 @default.
• W2085497894 citedByCount "20" @default.
• W2085497894 countsByYear W20854978942012 @default.
• W2085497894 countsByYear W20854978942013 @default.
• W2085497894 countsByYear W20854978942015 @default.
• W2085497894 countsByYear W20854978942016 @default.
• W2085497894 countsByYear W20854978942017 @default.
• W2085497894 crossrefType "journal-article" @default.
• W2085497894 hasAuthorship W2085497894A5006005996 @default.
• W2085497894 hasAuthorship W2085497894A5055756981 @default.
• W2085497894 hasAuthorship W2085497894A5068087465 @default.
• W2085497894 hasAuthorship W2085497894A5070276095 @default.
• W2085497894 hasAuthorship W2085497894A5077575893 @default.
• W2085497894 hasConcept C116569031 @default.
• W2085497894 hasConcept C134195300 @default.
• W2085497894 hasConcept C146686406 @default.
• W2085497894 hasConcept C147789679 @default.
• W2085497894 hasConcept C155647269 @default.
• W2085497894 hasConcept C161790260 @default.
• W2085497894 hasConcept C170493617 @default.
• W2085497894 hasConcept C17525397 @default.
• W2085497894 hasConcept C178790620 @default.
• W2085497894 hasConcept C185592680 @default.
• W2085497894 hasConcept C2777237805 @default.
• W2085497894 hasConcept C2778818089 @default.
• W2085497894 hasConcept C521398313 @default.
• W2085497894 hasConcept C52859227 @default.
• W2085497894 hasConcept C55493867 @default.
• W2085497894 hasConcept C555196967 @default.
• W2085497894 hasConcept C71240020 @default.
• W2085497894 hasConcept C93237805 @default.
• W2085497894 hasConceptScore W2085497894C116569031 @default.
• W2085497894 hasConceptScore W2085497894C134195300 @default.
• W2085497894 hasConceptScore W2085497894C146686406 @default.
• W2085497894 hasConceptScore W2085497894C147789679 @default.
• W2085497894 hasConceptScore W2085497894C155647269 @default.
• W2085497894 hasConceptScore W2085497894C161790260 @default.
• W2085497894 hasConceptScore W2085497894C170493617 @default.
• W2085497894 hasConceptScore W2085497894C17525397 @default.
• W2085497894 hasConceptScore W2085497894C178790620 @default.
• W2085497894 hasConceptScore W2085497894C185592680 @default.
• W2085497894 hasConceptScore W2085497894C2777237805 @default.
• W2085497894 hasConceptScore W2085497894C2778818089 @default.
• W2085497894 hasConceptScore W2085497894C521398313 @default.
• W2085497894 hasConceptScore W2085497894C52859227 @default.
• W2085497894 hasConceptScore W2085497894C55493867 @default.
• W2085497894 hasConceptScore W2085497894C555196967 @default.
• W2085497894 hasConceptScore W2085497894C71240020 @default.
• W2085497894 hasConceptScore W2085497894C93237805 @default.
• W2085497894 hasIssue "14" @default.
• W2085497894 hasLocation W20854978941 @default.
• W2085497894 hasOpenAccess W2085497894 @default.
• W2085497894 hasPrimaryLocation W20854978941 @default.
• W2085497894 hasRelatedWork W1991658803 @default.
• W2085497894 hasRelatedWork W2003453573 @default.
• W2085497894 hasRelatedWork W2008841073 @default.
• W2085497894 hasRelatedWork W2069659861 @default.
• W2085497894 hasRelatedWork W2082263875 @default.
• W2085497894 hasRelatedWork W2085497894 @default.
• W2085497894 hasRelatedWork W2087112255 @default.
• W2085497894 hasRelatedWork W2105159313 @default.
• W2085497894 hasRelatedWork W2801273486 @default.
• W2085497894 hasRelatedWork W2950057924 @default.
• W2085497894 hasVolume "26" @default.
• W2085497894 isParatext "false" @default.
• W2085497894 isRetracted "false" @default.
• W2085497894 magId "2085497894" @default.

• next