FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2085535952> ?p ?o ?g. }

• W2085535952 endingPage "2357" @default.
• W2085535952 startingPage "2353" @default.
• W2085535952 abstract "Abstract Two, symmetrical, mixed‐valence (MV), complex cations—{[Mo 2 (DAniF) 3 ] 2 (μ‐oxamidate)} + ( 1 + ) and {Mo 2 (DAniF) 3 ] 2 (μ‐dithiooxamidate)} + ( 2 + ; DAniF= N,N′ ‐di( p ‐anisyl)formamidinate)—are significantly differentiated in terms of electronic coupling between the two [Mo 2 ] units. For 1 + the intervalence (IV) charge‐transfer band in the near‐IR spectrum is truncated in half on the low‐energy side as predicted for MV compounds at the Class II–III limit (2 H ab / λ =1; for which H ab =electronic coupling matrix element and λ =reorganization energy). In contrast, the very strongly coupled analogue 2 + , as indicated by 2 H ab / λ =3.5 (> >1), exhibits a higher energy and more symmetrical IV band. As rare examples, this pair of MV species shows distinct optical behaviors for MV systems crossing the Class III region. Optical analysis and DFT calculations are carried out to elucidate the transformation from vibronic to electronic vertical transition." @default.
• W2085535952 created "2016-06-24" @default.
• W2085535952 creator A5019567696 @default.
• W2085535952 creator A5033101046 @default.
• W2085535952 creator A5045510170 @default.
• W2085535952 creator A5071074966 @default.
• W2085535952 creator A5071773009 @default.
• W2085535952 creator A5073987380 @default.
• W2085535952 creator A5080840986 @default.
• W2085535952 creator A5091345548 @default.
• W2085535952 date "2014-12-12" @default.
• W2085535952 modified "2023-10-18" @default.
• W2085535952 title "Distinguishing the Strength of Electronic Coupling for Mo₂-Containing Mixed-Valence Compounds within the Class III Regime" @default.
• W2085535952 cites W1514523329 @default.
• W2085535952 cites W1593507858 @default.
• W2085535952 cites W1602932472 @default.
• W2085535952 cites W1691067281 @default.
• W2085535952 cites W1965173894 @default.
• W2085535952 cites W1965459698 @default.
• W2085535952 cites W1967961588 @default.
• W2085535952 cites W1968355139 @default.
• W2085535952 cites W1974681020 @default.
• W2085535952 cites W1982057345 @default.
• W2085535952 cites W1983009723 @default.
• W2085535952 cites W1987214393 @default.
• W2085535952 cites W1987935734 @default.
• W2085535952 cites W1996123153 @default.
• W2085535952 cites W1996623634 @default.
• W2085535952 cites W1996718955 @default.
• W2085535952 cites W1997418114 @default.
• W2085535952 cites W1999473731 @default.
• W2085535952 cites W2005575796 @default.
• W2085535952 cites W2008523417 @default.
• W2085535952 cites W2019330754 @default.
• W2085535952 cites W2022706470 @default.
• W2085535952 cites W2024226106 @default.
• W2085535952 cites W2025201701 @default.
• W2085535952 cites W2026013633 @default.
• W2085535952 cites W2026512342 @default.
• W2085535952 cites W2028372250 @default.
• W2085535952 cites W2032587009 @default.
• W2085535952 cites W2032657118 @default.
• W2085535952 cites W2034402791 @default.
• W2085535952 cites W2044931258 @default.
• W2085535952 cites W2048081857 @default.
• W2085535952 cites W2057820608 @default.
• W2085535952 cites W2058202652 @default.
• W2085535952 cites W2060029714 @default.
• W2085535952 cites W2073006389 @default.
• W2085535952 cites W2088310002 @default.
• W2085535952 cites W2089605181 @default.
• W2085535952 cites W2093618780 @default.
• W2085535952 cites W2094970559 @default.
• W2085535952 cites W2096884462 @default.
• W2085535952 cites W2100032486 @default.
• W2085535952 cites W2105510993 @default.
• W2085535952 cites W2138289499 @default.
• W2085535952 cites W2148404437 @default.
• W2085535952 cites W2151440625 @default.
• W2085535952 cites W2153754246 @default.
• W2085535952 cites W2155774056 @default.
• W2085535952 cites W2316618673 @default.
• W2085535952 cites W2321239885 @default.
• W2085535952 cites W2328701768 @default.
• W2085535952 cites W2497007159 @default.
• W2085535952 cites W4213081055 @default.
• W2085535952 cites W4229625143 @default.
• W2085535952 cites W4241415947 @default.
• W2085535952 doi "https://doi.org/10.1002/chem.201406196" @default.
• W2085535952 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/25504781" @default.
• W2085535952 hasPublicationYear "2014" @default.
• W2085535952 type Work @default.
• W2085535952 sameAs 2085535952 @default.
• W2085535952 citedByCount "15" @default.
• W2085535952 countsByYear W20855359522015 @default.
• W2085535952 countsByYear W20855359522016 @default.
• W2085535952 countsByYear W20855359522017 @default.
• W2085535952 countsByYear W20855359522018 @default.
• W2085535952 countsByYear W20855359522019 @default.
• W2085535952 countsByYear W20855359522023 @default.
• W2085535952 crossrefType "journal-article" @default.
• W2085535952 hasAuthorship W2085535952A5019567696 @default.
• W2085535952 hasAuthorship W2085535952A5033101046 @default.
• W2085535952 hasAuthorship W2085535952A5045510170 @default.
• W2085535952 hasAuthorship W2085535952A5071074966 @default.
• W2085535952 hasAuthorship W2085535952A5071773009 @default.
• W2085535952 hasAuthorship W2085535952A5073987380 @default.
• W2085535952 hasAuthorship W2085535952A5080840986 @default.
• W2085535952 hasAuthorship W2085535952A5091345548 @default.
• W2085535952 hasConcept C103272658 @default.
• W2085535952 hasConcept C109214941 @default.
• W2085535952 hasConcept C113196181 @default.
• W2085535952 hasConcept C121332964 @default.
• W2085535952 hasConcept C131584629 @default.
• W2085535952 hasConcept C147597530 @default.
• W2085535952 hasConcept C168900304 @default.
• W2085535952 hasConcept C178790620 @default.
• W2085535952 hasConcept C181966813 @default.

• next