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• W2085568781 abstract "To investigate the influence of spatial extended direction and flexibility of secondary ligand on the resulting structure, eight new ferrocene-containing complexes with various dimensionalities have been synthesized by the reactions of CdII salts and 1,1′-bis(3-carboxy-1-oxopropyl)ferrocene (H2bfcs) with series of rationally selected N-heterocyclic spacers. When the small organic molecule 4-aminopyridine (apy) was employed as a secondary ligand, a one-dimensional (1D) linear complex {[Cd(bfcs)(apy)2]·H2O}n (1) was furnished, while the use of bis(azole) bridging ligands resulted in the formation of a 1D ribbon complex {[Cd(bfcs)(bbbm)1.5]·CH3OH·2H2O}n (2), a rare 1D quadruple-chain complex {[Cd(bfcs)(btmb)]·3H2O}n (3) and two two-dimensional (2D) puckered complexes {[Cd2(bfcs)2(pbbm)2]·2H2O}n (4) and {[Cd(bfcs)(bix)]·H2O}n (5) (bbbm = 1,1′-(1,4-butanediyl)bis-1H-benzimidazole, btmb = 4,4′-bis(1,2,4-triazole-1-ylmethyl)biphenyl, pbbm = 1,1′-(1,3-propanediyl)bis-1H-benzimidazole, bix = 1,4-bis(imidazole-1 -ylmethyl)benzene). In addition, the tripodal bridging secondary ligand led to an unusual three-dimensional (3D) layer pillar complex {[Cd2(bfcs)(titb)2Cl2]·2CH3OH·4H2O}n (6) (titb =1,3,5-tris(imidazol-1-ylmethyl)-2,4,6-trimethylbenzene). Employment of a flexible multidentate molecule tris(2-benzimidazolylmethyl)amine (ntb) as the secondary ligand gave birth to a mononuclear complex [Cd(bfcs)(ntb)]·DMF·5H2O (7) and a binuclear complex [Cd2(bfcs)(ntb)2]·bfcs·5H2O (8), in which ntb adopted the chelating coordination mode. It can be observed from the coordination architectures of 1−8 that secondary ligands had great effects on the spatial connective fashions of CdII centers, resulting in the formation of various dimensional complexes." @default.
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• W2085568781 date "2010-05-05" @default.
• W2085568781 modified "2023-10-14" @default.
• W2085568781 title "Secondary Ligand-Directed Assembly of Cd^II Coordination Architectures: From 0D to 3D Complexes Based on Ferrocenyl Carboxylate" @default.
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• W2085568781 doi "https://doi.org/10.1021/cg900566v" @default.
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