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- W2085585896 abstract "The excess volumes for the system cyclo-octane + cyclopentane have been measured at 288.15, 298.15, and 308.15 K with a dilution dilatometer. The excess volume has a minimum of −0.25 cm3 mol−1 at 288.15 K and becomes more negative with increase in temperature. Vapour pressures of the mixtures have been measured at the same temperatures by a precision static vapour pressure technique. The derived excess Gibbs free energy changes sign with composition and becomes more negative with increase in temperature. Excess enthalpies have been measured at 288.25 and 308.32 K with an isothermal displacement calorimeter. Measurements at 298.15 K have been presented previously. The excess enthalpy has a minimum of −33.7 J mol−1 at 288.25 K and becomes more negative with increase in temperature. Enthalpies calculated from the temperature dependence of the excess Gibbs free energy are consistent, within experimental error, with the direct measurements." @default.
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- W2085585896 date "1970-09-01" @default.
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- W2085585896 title "Excess enthalpies, excess volumes, and excess gibbs free energies for mixtures of cyclo-octane+cyclopentane at 288.15, 298.15, and 308.15 K" @default.
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- W2085585896 doi "https://doi.org/10.1016/0021-9614(70)90044-3" @default.
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