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- W2085596812 abstract "Abstract Infrared spectra (100–4000 cm −1 ) of the bis-ethylenediamine copper (II) chloride and thiosulfate and their N-deuterated analogues are reported. Reliable assignments of all the i.r. bands arising from the vibrations of the Cu(en) 2 2+ entity are proposed on both theoretical and experimental bases. Unexpected values of the isotopic shifts observed in the low frequency region reveal non-negligible couplings between CuN stretching and NCCN chelate ring motions. On the other hand, the investigation of the deuterated species leads to an unambiguous discrimination between group vibrations belonging either to Cu(en) 2 2+ or to S 2 O 3 2− ions. The frequency position of the six fundamentals of the thiosulfate ion suggests that S 2 O 3 2− anions vibrate, as free unperturbed C 3ν tetrahedrons, which therefore must be considered as nonbonding with respect to copper. Moreover, the thiosulfate are not affected by site splitting effects, confirming the assumption that the large Cu(en) 2 2+ chelate cations are likely to minimise crystal field effects." @default.
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- W2085596812 date "1976-01-01" @default.
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- W2085596812 title "Vibrational studies of metal-ethylenediamine thiosulfates—II. Infrared spectra of Cu(en)2S2O3 and some related bis-ethylenediamine complexes of copper (II)" @default.
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- W2085596812 doi "https://doi.org/10.1016/0584-8539(76)80086-4" @default.
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