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• W2085612075 abstract "To better understand the phase behavior of a pseudoceramide (SLE), a potential skin moisturizer and/or a drug carrier, we investigated the lipid–lipid interaction between SLE and a sterol-combined fatty acid (CEOS), which has a sterol ring and a carboxyl group in a molecule. X-ray analysis showed that a hexagonal packing (4.15 Å spacing) and a liquid-like packing (4.5 Å spacing) coexisted within the hydrocarbon chains of the SLE/CEOS (1/1 mole) lipid mixture. The structural characteristics were very similar to those of the SLE/stearic acid/cholesterol (1/1/1 mole) system, which was in a stable lamellar α-phase. However, in the SLE/stearic acid (1/1 mole) system, there was only a strong hexagonal reflection in the wide-angle X-ray profile. The melting enthalpy (23.9 kJ mol−1) and entropy (75.0 J mol−1K−1) of the SLE/CEOS system were also smaller than those (ΔHm= 43.9 kJ mol−1, ΔSm= 131.6 J mol−1K−1) of the SLE/stearic acid system. The X-ray data along with the DSC results suggested that the sterol ring of CEOS molecule contributed to the enhancement of molecular motion or the decrease in the molecular packing of lipids. A strong hydrogen bond between the carboxyl group of CEOS and the amide group of SLE molecule was also considered to be important for the formation of the stable α-phase, as suggested by FT-IR spectroscopy. Further, in the presence of water, the three artificial SC lipids, SLE/CEOS (1/1 mole), SLE/stearic acid/cholesterol (1/1/1 mole), and SLE/stearic acid (1/1 mole), were all capable of forming lamellar structures." @default.
• W2085612075 created "2016-06-24" @default.
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• W2085612075 date "1997-11-01" @default.
• W2085612075 modified "2023-10-17" @default.
• W2085612075 title "Intermolecular Interaction between a Synthetic Pseudoceramide and a Sterol-Combined Fatty Acid" @default.
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• W2085612075 doi "https://doi.org/10.1006/jcis.1997.5153" @default.
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