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• W2085628159 abstract "Photodissociation of CH3NH2 + has been studied using the DC sliced ion imaging technique and ab initio calculations in order to understand the formation of HCNH+, an important molecule in Titan's ionosphere. Our experimental and theoretical observations show that hydrogen loss from CH3NH2 + has two channels: one giving rise to the triplet species CH3NH+, while the other product is CH2NH2 +. The latter then decomposes further to form HCNH+. H2 loss from CH3NH2 + has only one channel, yielding CH2NH+. This species further loses H to form HCNH+. The branching ratio of the H, H2, and H+H2 loss channels is found to be 4.2:1:2.5. This is ascribed to the fact that, at these energies, the H loss has one stable triplet product channel, while most of the H2 loss product further decomposes to HCNH+." @default.
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• W2085628159 date "2010-01-15" @default.
• W2085628159 modified "2023-10-16" @default.
• W2085628159 title "PHOTODISSOCIATION DYNAMICS OF METHYLAMINE CATION AND ITS RELEVANCE TO TITAN'S IONOSPHERE" @default.
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• W2085628159 doi "https://doi.org/10.1088/0004-637x/710/1/112" @default.
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