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- W2085647187 abstract "The rotational distortion constants DJ and DJK have been evaluated for the partially deuteriated and tritiated silane and germane of the axially symmetric ZX3Y type. The procedure used is that of Dowling et al. which is based on Kivelson and Wilson's method and which makes use of the potential energy constants (F's) obtained for the symmetry coordinates. It has been found that the sign of DJK is positive when mY (mass of the Y atom) > mX (mass of the X atom) and negative when mY < mX. For the pyramidal XYZ2 (Y and Z are isotopes) molecules, the distortion constants R5 and δJ are positive and R6 is negative when mY > mZ; but R5 and δJ are negative and R6 is positive when mY < mZ." @default.
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- W2085647187 date "1962-01-01" @default.
- W2085647187 modified "2023-10-16" @default.
- W2085647187 title "Rotational distortion constants for axially symmetric ZX3Y (Z = Si or Ge; X, Y = H, D, or T) molecules; Sign of the constants in some molecules" @default.
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- W2085647187 doi "https://doi.org/10.1016/0022-2852(62)90006-1" @default.
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