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- W2085655133 abstract "Catalytic amount of vanadium reagent with tert-butylhydroperoxide as the oxidant was found to be an excellent oxidizing agent in aqueous medium. Vanadium pentoxide with aq tert-butylhydroperoxide readily oxidizes primary benzylic azides to the corresponding acids and secondary benzylic azides to the corresponding ketones in excellent yields. Further, vanadium pentoxide and aq tert-butylhydroperoxide combination turned out to be an effective catalyst for the oxidation of alcohols. Using vanadium pentoxide and aq tert-butylhydroperoxide primary alcohols were oxidized to the corresponding acids, whereas secondary alcohols underwent a smooth transformation to furnish corresponding ketones in excellent yields. All the oxidations are performed in water." @default.
- W2085655133 created "2016-06-24" @default.
- W2085655133 creator A5001629269 @default.
- W2085655133 creator A5044312898 @default.
- W2085655133 date "2011-11-01" @default.
- W2085655133 modified "2023-09-24" @default.
- W2085655133 title "Efficient synthesis of carbonyl compounds: oxidation of azides and alcohols catalyzed by vanadium pentoxide in water using tert-butylhydroperoxide" @default.
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- W2085655133 doi "https://doi.org/10.1016/j.tet.2011.08.080" @default.
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