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- W2085655888 abstract "A monolayer of the pH-responsive poly[2-(dimethylamino)ethyl methacrylate-block-methyl methacrylate] diblock copolymer [PDMAEMA-PMMA] was transferred from the air/water interface to a silicon substrate for evaluation as a tunable interlayer between biological material and solid substrates. Specular neutron reflectivity experiments revealed that the weak polyelectrolyte PDMAEMA chains at the solid/liquid interface can be reversibly activated by pH modulation. The thickness, scattering length density, and surface roughness of the polymer film can be systematically controlled by pH titration. As a simple model of plasma membranes, a lipid bilayer was deposited onto the polymer film. The membrane−substrate interaction was characterized by neutron reflectivity experiments, demonstrating that the membrane−substrate distance could be reversibly regulated by pH titration. These results confirm the potential of stimuli-responsive polymers for precise control of cell−surface interactions." @default.
- W2085655888 created "2016-06-24" @default.
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- W2085655888 date "2006-04-14" @default.
- W2085655888 modified "2023-10-03" @default.
- W2085655888 title "Reversible Activation of Diblock Copolymer Monolayers at the Interface by pH Modulation, 2: Membrane Interactions at the Solid/Liquid Interface" @default.
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- W2085655888 doi "https://doi.org/10.1021/jp054533b" @default.
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