Matches in SemOpenAlex for { <https://semopenalex.org/work/W2085656857> ?p ?o ?g. }
Showing items 1 to 74 of
74
with 100 items per page.
- W2085656857 endingPage "894" @default.
- W2085656857 startingPage "889" @default.
- W2085656857 abstract "An innovative green process of producing ɛ-caprolactam was proposed by integrating ammoximation and Beckmann rearrangement effectively. As a first part of the new process, TS-1 molecular sieve-catalyzed synthesis of cyclohexanone oxime from cyclohexanone, ammonia and hydrogen peroxide was carried out in a batch plant. Cyclohexane was used as the solvent in the three-phase reaction system. The influences of essential process parameters on ammoximation were investigated. Under the reaction conditions as catalyst content of 2.5% (by mass); H2O2/yclohexanone molar ratio of 1.10; NH3/cyclohexanone molar ratio of 2.20; reaction temperature of 343 K; reaction time of 5 h, high conversion of cyclohexanone and selectivity to oxime (both>99%) were obtained. Thus, the three-phase ammoximation process showed equal catalytic activity as TS-1 but much more convenient and simpler for the separation of catalyst in comparison to the industrial two-phase system with t-butanol used as solvent." @default.
- W2085656857 created "2016-06-24" @default.
- W2085656857 creator A5064744569 @default.
- W2085656857 creator A5077552407 @default.
- W2085656857 creator A5081185101 @default.
- W2085656857 date "2012-10-01" @default.
- W2085656857 modified "2023-10-09" @default.
- W2085656857 title "Ammoximation of Cyclohexanone to Cyclohexanone Oxime Catalyzed by Titanium Silicalite-1 Zeolite in Three-phase System" @default.
- W2085656857 cites W1971546292 @default.
- W2085656857 cites W1979650398 @default.
- W2085656857 cites W201189930 @default.
- W2085656857 cites W202404306 @default.
- W2085656857 cites W2032669365 @default.
- W2085656857 cites W2049504858 @default.
- W2085656857 cites W206647311 @default.
- W2085656857 cites W2087300708 @default.
- W2085656857 doi "https://doi.org/10.1016/s1004-9541(12)60414-5" @default.
- W2085656857 hasPublicationYear "2012" @default.
- W2085656857 type Work @default.
- W2085656857 sameAs 2085656857 @default.
- W2085656857 citedByCount "24" @default.
- W2085656857 countsByYear W20856568572013 @default.
- W2085656857 countsByYear W20856568572014 @default.
- W2085656857 countsByYear W20856568572015 @default.
- W2085656857 countsByYear W20856568572016 @default.
- W2085656857 countsByYear W20856568572017 @default.
- W2085656857 countsByYear W20856568572018 @default.
- W2085656857 countsByYear W20856568572019 @default.
- W2085656857 countsByYear W20856568572020 @default.
- W2085656857 countsByYear W20856568572022 @default.
- W2085656857 countsByYear W20856568572023 @default.
- W2085656857 crossrefType "journal-article" @default.
- W2085656857 hasAuthorship W2085656857A5064744569 @default.
- W2085656857 hasAuthorship W2085656857A5077552407 @default.
- W2085656857 hasAuthorship W2085656857A5081185101 @default.
- W2085656857 hasConcept C105281773 @default.
- W2085656857 hasConcept C161790260 @default.
- W2085656857 hasConcept C178790620 @default.
- W2085656857 hasConcept C179104552 @default.
- W2085656857 hasConcept C185592680 @default.
- W2085656857 hasConcept C2776341971 @default.
- W2085656857 hasConcept C2778237882 @default.
- W2085656857 hasConcept C2779537395 @default.
- W2085656857 hasConcept C2780450521 @default.
- W2085656857 hasConceptScore W2085656857C105281773 @default.
- W2085656857 hasConceptScore W2085656857C161790260 @default.
- W2085656857 hasConceptScore W2085656857C178790620 @default.
- W2085656857 hasConceptScore W2085656857C179104552 @default.
- W2085656857 hasConceptScore W2085656857C185592680 @default.
- W2085656857 hasConceptScore W2085656857C2776341971 @default.
- W2085656857 hasConceptScore W2085656857C2778237882 @default.
- W2085656857 hasConceptScore W2085656857C2779537395 @default.
- W2085656857 hasConceptScore W2085656857C2780450521 @default.
- W2085656857 hasIssue "5" @default.
- W2085656857 hasLocation W20856568571 @default.
- W2085656857 hasOpenAccess W2085656857 @default.
- W2085656857 hasPrimaryLocation W20856568571 @default.
- W2085656857 hasRelatedWork W1996727199 @default.
- W2085656857 hasRelatedWork W1998397475 @default.
- W2085656857 hasRelatedWork W2021338009 @default.
- W2085656857 hasRelatedWork W2378350430 @default.
- W2085656857 hasRelatedWork W2380898410 @default.
- W2085656857 hasRelatedWork W2381582875 @default.
- W2085656857 hasRelatedWork W2482066224 @default.
- W2085656857 hasRelatedWork W292483578 @default.
- W2085656857 hasRelatedWork W2952061665 @default.
- W2085656857 hasRelatedWork W2969748727 @default.
- W2085656857 hasVolume "20" @default.
- W2085656857 isParatext "false" @default.
- W2085656857 isRetracted "false" @default.
- W2085656857 magId "2085656857" @default.
- W2085656857 workType "article" @default.