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- W2085673752 abstract "Abstract Recently, experimental evidence has been obtained for the existence of dianionic carbon clusters as small as C2−7. So far, no theoretical evidence has been achieved for the electronic stability of C2−7, which is attributed to the underlying assumption of C2−7 having a linear structure. Linear, quasi-linear and trigonal planar atomic arrangements for C2−7 are discussed. At the latter structure C2−7 is predicted to be both stable with respect to vertical and adiabatic electron autodetachment and stable with respect to all framentation pathways. The reasons leading to the electronic stability of the trigonal C2−7 dianion are discussed and illuminated by drawing a connection with the structurally related MX2−3 alkali halides. Some remarks are made on larger dianionic carbon clusters." @default.
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- W2085673752 date "1993-07-01" @default.
- W2085673752 modified "2023-09-30" @default.
- W2085673752 title "The structure of small doubly negative carbon clusters" @default.
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- W2085673752 doi "https://doi.org/10.1016/0009-2614(93)80096-8" @default.
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