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• W2085696277 endingPage "3398" @default.
• W2085696277 startingPage "3385" @default.
• W2085696277 abstract "Five new selenophosphines (5a–d and 7) bearing organometallic Fe(κ2-dppe)(η5-C5Me5)C≡C– substituents were synthesized and structurally characterized in order to determine the steric and electronic parameters of the parent metallo-phosphines (1a–d and 2). Their cone angles were estimated from available structural data, and their electronic parameters were derived from the 1JPSe coupling constants. DFT calculations suggest that 1JPSe constants can be used to determine their electronic parameters in spite of the existence of the low-lying excited states for 5a–d. Strong solvent effects were evidenced on 1JPSe, stressing the need to use a single solvent (CDCl3) for measuring these coupling constants if comparison of the electronic parameter of these with existing data is sought. Among the parent metallo-phosphines, 2 appears to be the most electron donating ligand by far. According to its 1JPSe value, it resembles a tris(alkyl)phosphine but presents a significantly larger Tolman cone angle (θT ≈ 172°) than PPh3 (θT ≈ 145°)." @default.
• W2085696277 created "2016-06-24" @default.
• W2085696277 creator A5004684676 @default.
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• W2085696277 creator A5030028782 @default.
• W2085696277 creator A5049143428 @default.
• W2085696277 creator A5063157897 @default.
• W2085696277 date "2014-06-23" @default.
• W2085696277 modified "2023-10-18" @default.
• W2085696277 title "Selenophosphine Derivatives with Pendant Electron-Rich Fe(κ²-dppe)(η⁵-C₅Me₅)C≡C– Substituents" @default.
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