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- W2085709145 abstract "Selenium is a known toxic element released in the environment by anthropogenic activities. The present study is devoted to the aqueous sorption behaviour of selenium oxyanions (selenate and selenite) on a reference oxide surface, namely rutile TiO2. Batch sorption kinetics and isotherms have been studied using different physico-chemical conditions of the solution (changes of pH and ionic strength). The sorption was favoured for both anions in acidic conditions, in agreement with a surface complexation mechanism and CD-MUSIC predictions. Spectroscopic investigations of the sorbed rutile powder were also consistent with such a mechanism. EXAFS spectra confirmed that for selenite anions, an inner-sphere mechanism was the most probable process observed. Dynamic sorption experiments using a column filled with rutile powder also substantiated that a part of the surface complexes follows the inner-sphere mechanism, but also evidenced that an outer-sphere mechanism cannot be excluded, especially for selenate anions." @default.
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- W2085709145 date "2011-05-01" @default.
- W2085709145 modified "2023-10-15" @default.
- W2085709145 title "Sorption of selenium oxyanions on TiO2 (rutile) studied by batch or column experiments and spectroscopic methods" @default.
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- W2085709145 doi "https://doi.org/10.1016/j.jhazmat.2011.02.090" @default.
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