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• W2085709630 abstract "Recent studies have revealed that side-chain liquid-crystal polymers typically exhibit shear-induced phases within the isotropic melt. From rheo-birefringence measurements, we demonstrate that those shear-induced phases are not coupled with conventional orientational-order fluctuations. From viscoelastic measurements, we demonstrate that the melt is not liquid but gel-like one hundred degrees away from the glass transition temperature and up to 15 °C away from the Isotropic-Nematic phase transition. Finally, rheo-SANS experiments show that the polymer chain is deformed at time scales compatible with this supra-molecular cohesion. The solicitation of this gel-like state explains the emergence of non-linear phenomena." @default.
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• W2085709630 date "2005-12-01" @default.
• W2085709630 modified "2023-10-18" @default.
• W2085709630 title "Unexpected giant elasticity in side-chain liquid-crystal polymer melts: A new approach for the understanding of shear-induced phase transitions" @default.
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• W2085709630 doi "https://doi.org/10.1209/epl/i2004-10552-3" @default.
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