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- W2085719740 abstract "The reaction of [Os3(CO)10(NCMe)2] (1) with aldehydes in refluxing cyclohexane affords the metal clusters [Os3(CO)10(μ-H)(COR)] (2, R = Me, Ph, CH2Ph or C6H13) in ca. 50% yield. The compound 2 (R = CH2Ph) undergoes hydrogenation under pressure to give the corresponding alcohol, while decarbonylation occurs in the presence of Me3NO to give the Me3N-substituted derivative [Os3(CO)9(NMe3)(μ-H)(COCH2Ph)] in 90% yield." @default.
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- W2085719740 date "1986-06-01" @default.
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- W2085719740 title "Synthetic studies of the reaction between aldehydes and the triosmium cluster [Os3(CO)10(NCMe)2]" @default.
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- W2085719740 doi "https://doi.org/10.1016/0022-328x(86)80175-9" @default.
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