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- W2085751572 abstract "We have observed several new spectral features in the fluorescence of cesium atoms implanted in the hcp phase of solid helium following laser excitation to the 62P states. Based on calculations of the emission spectra using semiempirical Cs-He pair potentials the newly discovered lines can be assigned to the decay of specific Cs*Hen exciplexes: an apple-shaped Cs(APi3/2)He2 and a dumbbell-shaped Cs(APi1/2)Hen exciplex with a well-defined number n of bound helium atoms. While the former has been observed in other environments, it was commonly believed that exciplexes with n>2 might not exist. The calculations suggest Cs(APi1/2)He7 to be the most probable candidate for that exciplex, in which the helium atoms are arranged on a ring around the waist of the dumbbell-shaped electronic density distribution of the cesium atom." @default.
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- W2085751572 date "2005-02-14" @default.
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- W2085751572 title "Discovery of Dumbbell-Shaped<mml:math xmlns:mml=http://www.w3.org/1998/Math/MathML display=inline><mml:msup><mml:mrow><mml:mi mathvariant=normal>C</mml:mi><mml:mi mathvariant=normal>s</mml:mi></mml:mrow><mml:mo>*</mml:mo></mml:msup><mml:msub><mml:mrow><mml:mi mathvariant=normal>H</mml:mi><mml:mi mathvariant=normal>e</mml:mi></mml:mrow><mml:mi>n</mml:mi></mml:msub></mml:math>Exciplexes in Solid<mml:math xmlns:mml=http://www.w3.org/1998/Math/MathML display=inline><mml:…" @default.
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- W2085751572 doi "https://doi.org/10.1103/physrevlett.94.063001" @default.
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