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• W2085757874 abstract "Linear viscoelasticity experiments are shown to follow a regular pattern near the gel point of chemical and physical gels. Experimental observations are reviewed for the three critical exponents of rheology: the relaxation exponent (n) for the material directly at the gel point, the critical exponent (α) of the divergence of the longest relaxation time in the approach of the gel point, and the exponent (κ) for the rate of change of the spectrum at the transition. The molecular weight of the precursor is an important parameter which has been studied recently. Other parameters are addition of diluent (solvent), off-balancing of stoichiometry, and bulkiness of crosslinking points." @default.
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• W2085757874 date "1994-01-01" @default.
• W2085757874 modified "2023-09-25" @default.
• W2085757874 title "Experimental observation of the molecular weight dependence of the critical exponents for the rheology near the gel point" @default.
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• W2085757874 doi "https://doi.org/10.1016/0966-7822(94)90008-6" @default.
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