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- W2085778520 abstract "Five type B or type C bands in the gas phase infrared spectrum of CHD2Cl and two type C bands of CHD2CCH have been analyzed with a resolution of 0.2 cm−1. All other fundamental vibrations have been located. Accurate determinations of (A0-B0) for each molecule are obtained from ground state combination differences, from which A0 values are derived using microwave estimates of B0 and C0. The combination of one A0 rotational constant with B0 and C0 constants for all other isotopic species enables the ground state molecular geometry to be fixed within narrow limits, assuming that zero-point energy effects cause a shortening of the CH bond length by 0.002 Å on deuteration. The CH bond lengths are in almost precise agreement with the values predicted from the position of the sole CH stretching vibration frequency for each molecule." @default.
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- W2085778520 date "1973-05-01" @default.
- W2085778520 modified "2023-10-18" @default.
- W2085778520 title "Infrared spectra of CHD2Cl and CHD2CCH and the geometries of methyl chloride and propyne" @default.
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- W2085778520 doi "https://doi.org/10.1016/0022-2852(73)90039-8" @default.
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