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- W2085781083 abstract "Multilayers of gold nanoclusters (GNCs) coated with a thin Pd layer were constructed using GNCs modified with self-assembled monolayers (SAMs) of mercaptoundecanoic acid and a polyallylamine hydrochloride (PAH) multilayer assembly, which has been reported to act as a three-dimensional electrode. SAMs were removed from GNCs by electrochemical anodic decomposition and then a small amount of Pd was electrochemically deposited on the GNCs. The kinetics of the oxygen reduction reaction (ORR) on the Pd modified GNC/PAH multilayer assembly was studied using a rotating disk electrode, and a significant increase in the ORR rate was observed after Pd deposition. Electrocatalytic activities in alkaline and acidic solutions were compared both for the GNC multilayer electrode and Pd modified GNC electrode." @default.
- W2085781083 created "2016-06-24" @default.
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- W2085781083 date "2011-08-01" @default.
- W2085781083 modified "2023-10-01" @default.
- W2085781083 title "Construction of multilayers of bare and Pd modified gold nanoclusters and their electrocatalytic properties for oxygen reduction" @default.
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- W2085781083 doi "https://doi.org/10.1088/1468-6996/12/4/044606" @default.
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