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• W2085823060 endingPage "A795" @default.
• W2085823060 startingPage "A787" @default.
• W2085823060 abstract "The electric-field gradient tensor at the iron nucleus in ferrous (${mathrm{Fe}}^{2+}$) compounds is investigated. One sees that under the combined action of axial and rhombic crystalline fields and the spin-orbit interaction, the ferrous-ion $(^{5}D,3{d}^{6}){d}_{ensuremath{epsilon}}$ states produce a large, temperature-dependent, contribution to the electric-field gradient tensor. It is found that this direct contribution is diminished by that from the lattice itself (the second-order axial and rhombic components of the crystalline field), as well as Sternheimer polarization effects and covalency. The results of this investigation are then applied to Mossbauer results in FeSi${mathrm{F}}_{6}$ifmmodecdotelsetextperiodcenteredfi{}6${mathrm{H}}_{2}$O to obtain an estimate of the electric quadrupole moment of ${mathrm{Fe}}^{57m}(0.29ifmmodepmelsetextpmfi{}0.02mathrm{b})$, which is in agreement with that from ferric (${mathrm{Fe}}^{3+}$) studies. Finally, estimates also based upon Mossbauer measurements, are made of the ${d}_{ensuremath{epsilon}}$ energy splittings in the ferrous compounds, FeSi${mathrm{F}}_{6}$ifmmodecdotelsetextperiodcenteredfi{}6${mathrm{H}}_{2}$O, FeS${mathrm{O}}_{4}$ifmmodecdotelsetextperiodcenteredfi{}7${mathrm{H}}_{2}$O, Fe${mathrm{C}}_{2}$${mathrm{O}}_{4}$ifmmodecdotelsetextperiodcenteredfi{}2${mathrm{H}}_{2}$O, Fe${(mathrm{N}{mathrm{H}}_{4}mathrm{S}{mathrm{O}}_{4})}_{2}$ifmmodecdotelsetextperiodcenteredfi{}6${mathrm{H}}_{2}$O, FeS${mathrm{O}}_{4}$, Fe${mathrm{Cl}}_{2}$ifmmodecdotelsetextperiodcenteredfi{}4${mathrm{H}}_{2}$O, and Fe${mathrm{F}}_{2}$." @default.
• W2085823060 created "2016-06-24" @default.
• W2085823060 creator A5064721395 @default.
• W2085823060 date "1964-02-03" @default.
• W2085823060 modified "2023-10-09" @default.
• W2085823060 title "Electric-Field Gradient Tensor in Ferrous Compounds" @default.
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• W2085823060 doi "https://doi.org/10.1103/physrev.133.a787" @default.
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