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- W2085855383 abstract "Abstract By oxidation of the pure fluoro-chloro-osmates(IV ) with BrF 3 in dichlorom ethane the mixed pentavalent complexes [OsF 5 Cl] - , cis-[OsF 4 Cl 2 ] - , fac-[OsF 3 Cl 3 ] - and cis-[OsF 2 Cl4] - are formed without replacement of ligands. Trans-[OsF 4 Cl 2 ] - and trans-[OsF 2 Cl 4 ] - are generated from the corresponding osmates(IV) by oxidation with PbO 2 in dichloromethane under addition of trifluoroacetic acid. The vibrational spectra o f the mixed ligand complexes are assigned according to point groups D 4h , C 4v , C 3v and C 2v . The increased bond strength com pared with the corresponding Os(IV ) complexes is indicated by a significant shift to higher energy by about 5 -15% . The Os -Cl stretching vibration of [OsF 5 Cl] - and also the symmetric ClOsCl of trans-[OsF 4 Cl 2 ] - is split by the isotopes 35 Cl and 37 Cl, showing two and three well resolved sharp Raman lines in the expected ratio of intensities, respectively." @default.
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- W2085855383 date "1986-07-01" @default.
- W2085855383 modified "2023-09-24" @default.
- W2085855383 title "Darstellung und Schwingungsspektren von Fluoro-Chloro-Osmaten(V)/ Preparation and Vibrational Spectra of Fluoro-Chloro-Osm ates(V)" @default.
- W2085855383 doi "https://doi.org/10.1515/znb-1986-0715" @default.
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