Matches in SemOpenAlex for { <https://semopenalex.org/work/W2085887155> ?p ?o ?g. }
Showing items 1 to 70 of
70
with 100 items per page.
- W2085887155 endingPage "480" @default.
- W2085887155 startingPage "477" @default.
- W2085887155 abstract "The charge-transfer complex formed by the interaction of an aliphatic amine, such as n-butylamine (nBA), and carbon tetrachloride (CCl4) in dimethylsulphoxide (DMSO) initiates polymerization of methyl methacrylate (MMA) at 30°. The rate of polymerization is given by Rp = k[MMA]0.83 [nBA]0.5 [CCl4]0.5 when [CCl4]/[nBA] is ⩽ 1. When [CCl4]/[nBA] > 1, Rp is independent of [CCl4] and Rp = k[MMA]1.46 [nBA]0.5. The average rate constants are (1.42 ± 0.05) × 10−6 1 mol−1 sec−1 in terms of MMA and (2.20 ± 0.06) × 10−6 sec−1 at 30° for higher and lower concentration of carbon tetrachloride respectively. A charge-transfer mechanism for polymerization is suggested." @default.
- W2085887155 created "2016-06-24" @default.
- W2085887155 creator A5015980858 @default.
- W2085887155 creator A5027470924 @default.
- W2085887155 date "1982-01-01" @default.
- W2085887155 modified "2023-10-11" @default.
- W2085887155 title "Polymerization of methyl methacrylate by charge-transfer complex using n-butyl amine and carbon tetrachloride in dimethylsulphoxide" @default.
- W2085887155 cites W1930515130 @default.
- W2085887155 cites W1982577828 @default.
- W2085887155 cites W1996249908 @default.
- W2085887155 cites W2003097169 @default.
- W2085887155 cites W2011687642 @default.
- W2085887155 cites W2056877388 @default.
- W2085887155 cites W2089596504 @default.
- W2085887155 cites W2096465933 @default.
- W2085887155 cites W2133218451 @default.
- W2085887155 cites W2144613900 @default.
- W2085887155 cites W2161721145 @default.
- W2085887155 doi "https://doi.org/10.1016/0014-3057(82)90047-7" @default.
- W2085887155 hasPublicationYear "1982" @default.
- W2085887155 type Work @default.
- W2085887155 sameAs 2085887155 @default.
- W2085887155 citedByCount "21" @default.
- W2085887155 countsByYear W20858871552012 @default.
- W2085887155 countsByYear W20858871552013 @default.
- W2085887155 countsByYear W20858871552018 @default.
- W2085887155 crossrefType "journal-article" @default.
- W2085887155 hasAuthorship W2085887155A5015980858 @default.
- W2085887155 hasAuthorship W2085887155A5027470924 @default.
- W2085887155 hasConcept C131779359 @default.
- W2085887155 hasConcept C178790620 @default.
- W2085887155 hasConcept C185592680 @default.
- W2085887155 hasConcept C188027245 @default.
- W2085887155 hasConcept C2777359374 @default.
- W2085887155 hasConcept C2777935641 @default.
- W2085887155 hasConcept C2778179251 @default.
- W2085887155 hasConcept C44228677 @default.
- W2085887155 hasConcept C521977710 @default.
- W2085887155 hasConcept C525849907 @default.
- W2085887155 hasConceptScore W2085887155C131779359 @default.
- W2085887155 hasConceptScore W2085887155C178790620 @default.
- W2085887155 hasConceptScore W2085887155C185592680 @default.
- W2085887155 hasConceptScore W2085887155C188027245 @default.
- W2085887155 hasConceptScore W2085887155C2777359374 @default.
- W2085887155 hasConceptScore W2085887155C2777935641 @default.
- W2085887155 hasConceptScore W2085887155C2778179251 @default.
- W2085887155 hasConceptScore W2085887155C44228677 @default.
- W2085887155 hasConceptScore W2085887155C521977710 @default.
- W2085887155 hasConceptScore W2085887155C525849907 @default.
- W2085887155 hasIssue "6" @default.
- W2085887155 hasLocation W20858871551 @default.
- W2085887155 hasOpenAccess W2085887155 @default.
- W2085887155 hasPrimaryLocation W20858871551 @default.
- W2085887155 hasRelatedWork W1985618750 @default.
- W2085887155 hasRelatedWork W2010483118 @default.
- W2085887155 hasRelatedWork W2049509781 @default.
- W2085887155 hasRelatedWork W2059513737 @default.
- W2085887155 hasRelatedWork W2065487230 @default.
- W2085887155 hasRelatedWork W2066819043 @default.
- W2085887155 hasRelatedWork W2078631087 @default.
- W2085887155 hasRelatedWork W2084005834 @default.
- W2085887155 hasRelatedWork W2318059896 @default.
- W2085887155 hasRelatedWork W2121919670 @default.
- W2085887155 hasVolume "18" @default.
- W2085887155 isParatext "false" @default.
- W2085887155 isRetracted "false" @default.
- W2085887155 magId "2085887155" @default.
- W2085887155 workType "article" @default.