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• W2085887320 endingPage "1786" @default.
• W2085887320 startingPage "1781" @default.
• W2085887320 abstract "The reactions of ruthenium(III) chloride (1 mol) with acetylacetonylidene-4-aminoantipyrine (HL1), monobenzoylacetylacetonylidene-4-aminoantipyrine (HL2), dibenzoylmethanylidene-4-aminoantipyrine (HL3) and antipyrine-4-azo-β-ethylacetoacetate (HL4) (1 mol) produce complexes of the general formula RuHLCl3. The ligand antipyrine-4-azo-β-acetylacetone (HL5) (1 mol) reacts with RuCl3·3H2O to produce RuL5 Cl2(H2O)·H2O. The ligands HL1-HL3 react as neutral bidentates in the ketoenamine form, whereas HL4 reacts as a neutral bidentate in the hydrazo form. HL5 reacts as a monobasic tridentate in the azo form. The complexes were characterized using a variety of analytical, spectral, magnetic and thermal measurements. The electrochemical redox properties of complexes I–V have been studied by cyclic voltammetry in acetonitrile. The chloro-bridged dimer complexes I–IV showed two reversible diffusion-controlled oxidation peaks. The first was attributed to the oxidation of the ruthenium(III) to the corresponding mixed-valence complex and the second to the ruthenium(IV) complex. The redox properties of complexes I–IV are dependent on the nature of ligand. The monomeric complex V has quite different properties." @default.
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• W2085887320 date "1994-06-01" @default.
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• W2085887320 title "Synthesis, characterization and electrochemical properties of β-diketone complexes of ruthenium(III)" @default.
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• W2085887320 doi "https://doi.org/10.1016/s0277-5387(00)80110-2" @default.
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