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- W2085918076 abstract "1d-(1,2,4/3)-2,3,4-Tri-O-benzyl-5-(trityloxymethyl)-5-cyclohexene-1,2,3,4-tetrol (5a) and its 1l-(1,3/2,4) isomer (5b) were prepared from d-glucose, and they underwent ready mutual interconversion through an SN2 procedure employing a benzoic acid-diethyl azodicarboxylate-triphenylphosphine system and subsequent basic hydrolysis. Azido, phthalimido, and even more complex nucleophile groups could similarly also substitute the allylic hydroxyl groups of 5a and 5b by using the same system, with a few different results between 5a and 5b." @default.
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- W2085918076 date "1986-10-01" @default.
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- W2085918076 title "Displacement of “pseudoanomeric” hydroxyl groups by using the diethyl azodicarboxylate-triphenylphosphine system" @default.
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- W2085918076 doi "https://doi.org/10.1016/s0008-6215(00)90027-2" @default.
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