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- W2085926671 abstract "Abstract In this chapter, we discuss our approach to the syntheses of aigialomycin C and D via a ring-closing metathesis (RCM) approach. While we did not succeed in reaching the final desired targets, the syntheses of epi -aigialomycin D and deoxy -aigialomycin C are described via a remote stereocontrolled RCM macrocyclization. The key reaction involved a highly chemo- and diastereoselective RCM protocol for the formation of the macrocyclic core. In addition, we observed that a remote stereocenter influenced the RCM reaction with respect to macrocyclization." @default.
- W2085926671 created "2016-06-24" @default.
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- W2085926671 date "2013-07-18" @default.
- W2085926671 modified "2023-09-27" @default.
- W2085926671 title "ChemInform Abstract: A Chemo- and Diastereoselective Ring Closing Metathesis Macrocyclization Approach to the Total Syntheses of Aigialomycin C and D" @default.
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- W2085926671 doi "https://doi.org/10.1002/chin.201332230" @default.
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